No the permission for polygny is bound to certain conditions which no normal human being is able to fulfill to 100%. That's why Allah added the words like "as much as"if you can"fear"(see in 4:3).
Secondly it is human nature that a wife wouldn't like to share her husband and Allah knows his creation best.
Finally scholars consider the condition of being the lonely wife added in a 'aqd nikah as valid.
So there's no reason considering opposing this per se as kufr. Unless a woman says Allah is unjust by ordering or allowing this.