No. according to shia scholars this is not true. Ali s.a. was not there at Miraj. prophet only saw an angel who was in the shape of Ali sa and also Allah talked prophet with voice of Ali as and Allah said somethings to prophet about Ali as. but as I searched in many hadith nothing mentioned Ali as himself was there.
the only authentic Hadith I found about Ali a.s. and Miraj are:
In the book Kashf al‑Ghummah, it has been narrated from Abdullah ibn
Umar that: "I heard someone ask the Prophet of Allah , `With what
voice did Allah, the Glorified and High, speak to you in on the night
of the Me'raj?"
The Prophet replied, "My Lord spoke to me with the voice of 'Ali ibn
Abi Talib and said, `O' Ahmad! I am an Entity that is not like
anything else. I can not be compared to anything else and I know all
the secrets of your heart. With the exception of 'Ali ibn Abi Talib ,
you have no other close friend. Thus, I speak to you with the voice of
'Ali ibn Abi Talib so that your heart will be at ease.""
From Kashf al-Ghummah, Vol. 1, p. 106, Fee mahabbati al-rasooli (s)
iyyahu wa tahreedahu alaa mahabbatihi wa muwaalaatihi wa nahyuhu an
baghdihi.
source
also in the Hadith Book Bihar al Anwar vol.9 page 76 it is narrated from Imam Sadiq a.s. that prophet said:
when reached where there was nothing between me and Allah and there
was no angel or prophet. I did not asked anything unless I received
better of it. at that time this came to my mind:
You are only a warner, and for every Ummah is a guide. http://tanzil.net/#13:7
so I asked Allah: O my trainer you placed me Warner. but who is Guide
of m Ummah? Allah replied O Muhammad! he is Ali Ibn Abi Talib. he is
guide and leader of who found my way and who are pious...
translated from this source
also these hadiths are narrated in Bihar al Anwar
“It is related that Muhammad declared that on the night of Ascension,
the Most High commanded me to inquire of the past prophets for what
reason they were exalted to that rank, and they all testified, “We
were raised up on account of your Prophetical Office, and the Imamate
of Ali Ibn Abu Talib, and the Imams of your posterity”. A divine voice
then commanded, ‘look on the right side of the empyrean’. I looked and
saw the similitude of Ali, and Hasan, and Husain, and Ali ibn
al-Husain, and Muhammad Bakir, and Jafar as-Sadiq, and Musa Kazim, and
Ali ibn Musa-ar-Reza, and Muhammad Taki, and Ali Naqi, and Hasan
Askhari, and Mahdi all performing prayers in a sea of light. ‘These’,
said the Most High, “are my proofs, Vicegerents, and friends, and the
last of them will take vengeance on my enemies.”
and
‘The Prophet declared that when he performed the Ascension, the angels
inquired very particularly about Ali. ‘When I arrived,’ he continued,
‘at the fourth heaven, I saw the angel of death, who said that it was
his office to take the soul of every creature by God’s command; but in
the case of you and Ali, I will have to take your consent.’ When I
came under the empyrean, I saw Ali ibn Abu Talib standing there, and
said to him, ‘O Ali have you got there before me?’ ‘Whom are you
addressing’, asked Gabriel. ‘My brother’, I replied. ‘This is not
Ali,’ said he, ‘but an angel of the Merciful God, whom he created in
the likeness of Ali and when those of us privileged to approach near
the Deity wish to behold Ali, we visit this angel.”
and
And so Jesus and Moses and Abraham all inquired about Ali and
congratulated Muhammad on having left so good a Caliph in his place.
The Apostle further related, “On the night of MERAJ, on every one of
the curtains of light and on every one of the pillars of the empyrean
to which I came, I saw written; there is no God but Allah, Muhammad is
the Apostle of God, and Ali ibn Abu Talib is the commander of the
Faithful.”
